Metal-organic frameworks based on trigonal prismatic building blocks and the new "acs" topology

被引：273

作者：

Sudik, AC ^{[1
]}

Côté, AP ^{[1
]}

Yaghi, OM ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 09期

关键词：

D O I：

10.1021/ic050064g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cationic and mixed-valent forms of Fe3O(CO2)(6) trigonal prismatic clusters have been linked by ditopic links, namely, 1,4-benzene-dicarboxylate (1,4-BDC) and 1,3-benzenedicarboxylate (1,3-BDC), to produce two 3-periodic metal-organic frameworks (MOFs), [Fe3O(1,4-BDC)(3)(DMF)(3)][FeCl4]center dot(DMF)(3) (MOF-235) and Fe3O(1,3-BDC)(3)(py)(3)center dot(py)(0.5)(H2O)(1.5) (MOF-236) (DMF = N,N-dimethylformamide, py = pyridine), respectively. These MOFs exemplify a new, high-symmetry topology termed acs which we identify here as the default arrangement for linking trigonal prisms together.

引用

页码：2998 / 3000

页数：3

共 18 条

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