Gallium enolate-mediated intermolecular aldol reaction and addition reaction of α-bromoketone with imine

被引：17

作者：

Han, Y ^{[1
]}

Huang, YZ ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 42期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0040-4039(98)01661-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of alpha-bromoketone with gallium triiodide or methyl galliumiodide prepared in situ provides gallium enolates which react with carbonyl compounds or imines to give beta - hydroxy ketones or beta -phenylamino ketones effectively in moderate yields (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：7751 / 7754

页数：4

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