Transfer hydrogenation of olefins catalysed by nickel nanoparticles

被引：67

作者：

Alonso, Francisco ^{[1
]}

Riente, Paola

Yus, Miguel

机构：

[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, E-03080 Alicante, Spain

来源：

TETRAHEDRON | 2009年 / 65卷 / 51期

关键词：

Hydrogen transfer; Reduction; Olefins; Nickel nanoparticles; NICL2-LI-ARENE CAT. COMBINATION; CARBONYL-COMPOUNDS; ORGANIC-COMPOUNDS; REDUCTIVE AMINATION; ALPHA-ALKYLATION; ALLYLIC ALCOHOLS; REDUCING SYSTEM; METHYL KETONES; COMPLEXES; PALLADIUM;

D O I：

10.1016/j.tet.2009.10.057

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nickel nanoparticles have been found to effectively catalyse the hydrogen-transfer reduction of a variety of non-functionalised and functionalised olefins using 2-propanol as the hydrogen donor. The heterogeneous process has been shown to be highly chemoselective for certain substrates, with all the corresponding alkanes being obtained in high yields. A synthesis of the natural dihydrostilbene brittonin A is also reported based on the use of nickel nanoparticles. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：10637 / 10643

页数：7

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