Efficient Co(II) heterogeneously catalysed synthesis of α-aminonitriles at room temperature via Strecker-type reactions

被引：28

作者：

Rajabi, Fatemeh ^{[1
]}

Ghiassian, Sara ^{[2
]}

Saidi, Mohammad Reza ^{[2
]}

机构：

[1] Payame Noor Univ, Dept Sci, Qazvin, Iran

[2] Sharif Univ Technol, Dept Chem, Tehran, Iran

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 08期

关键词：

SOLVENT-FREE SYNTHESIS; AMINO-ACIDS; ASYMMETRIC-SYNTHESIS; COBALT COMPLEX; KETIMINES; KETONES;

D O I：

10.1039/c0gc00047g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An environmentally friendly and highly active mesoporous Co(II) complex on mesoporous SBA-15 material could be used as an easily recoverable catalyst for the synthesis of alpha-aminonitriles from a wide range of aldehydes/ketones and primary or secondary amines with good to excellent conversions yields at room temperature under solventless conditions. The catalyst can be recovered by simple filtration and could be reused at least 10 times without loss of catalytic activity.

引用

收藏

页码：1349 / 1352

页数：4

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