Synthetic control of framework zinc purinate crystallisation and properties of a large pore, decorated, mixed-linker RHO-type ZIF

被引：31

作者：

Kahr, Juergen ^{[1
]}

Mowat, John P. S. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Morris, Russell E. ^{[1
]}

Fairen-Jimenez, David ^{[2
]}

Wright, Paul A. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Edinburgh, Inst Mat & Proc, Sch Engn, Edinburgh EH8 9YL, Midlothian, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 53期

基金：

英国工程与自然科学研究理事会;

关键词：

IMIDAZOLATE FRAMEWORKS;

D O I：

10.1039/c2cc32927a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel form of mixed-linker ZIF with the RHO topology is one of four zinc-imidazolate frameworks prepared with purine and 2-nitroimidazole. In this structure the linkers order to give a large pore solid with a high pore volume and an unusual symmetry and linker orientation. It possesses extra-framework zinc imidazolate units decorating the internal surface which can be removed to give high porosity.

引用

页码：6690 / 6692

页数：3

共 11 条

[1] High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores [J].

An, Jihyun ;

Geib, Steven J. ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) :38-+

[2] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[3] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties [J].

Banerjee, Rahul ;

Furukawa, Hiroyasu ;

Britt, David ;

Knobler, Carolyn ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3875-+

[4] Mixed-component metal-organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications [J].

Burrows, Andrew D. .

CRYSTENGCOMM, 2011, 13 (11) :3623-3642

[5]

Frenkel D., 2002, UNDERSTANDING MOL SI, V2nd edn

[6] Zeolite a imidazolate frameworks [J].

Hayashi, Hideki ;

Cote, Adrien P. ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

NATURE MATERIALS, 2007, 6 (07) :501-506

[7] Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies [J].

Huang, XC ;

Lin, YY ;

Zhang, JP ;

Chen, XM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (10) :1557-1559

[8] Supramolecular medicinal chemistry: Mixed-ligand coordination complexes [J].

Ma, Zhenbo ;

Moulton, Brian .

MOLECULAR PHARMACEUTICS, 2007, 4 (03) :373-385

[9] A Combined Experimental-Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks [J].

Morris, William ;

Leung, Belinda ;

Furukawa, Hiroyasu ;

Yaghi, Omar K. ;

He, Ning ;

Hayashi, Hideki ;

Houndonougbo, Yao ;

Asta, Mark ;

Laird, Brian B. ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (32) :11006-11008

[10] Exceptional chemical and thermal stability of zeolitic imidazolate frameworks [J].

Park, Kyo Sung ;

Ni, Zheng ;

Cote, Adrien P. ;

Choi, Jae Yong ;

Huang, Rudan ;

Uribe-Romo, Fernando J. ;

Chae, Hee K. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (27) :10186-10191

← 1 2 →