Grain size effect on the nonlinear dielectric properties of barium titanate ceramics

被引:103
作者
Curecheriu, Lavinia [1 ]
Buscaglia, Maria Teresa [2 ]
Buscaglia, Vincenzo [2 ]
Zhao, Zhe [3 ]
Mitoseriu, Liliana [1 ]
机构
[1] Alexandru Ioan Cuza Univ, Dept Phys, Iasi 700506, Romania
[2] CNR, Inst Energet & Interphases IENI, I-16149 Genoa, Italy
[3] Univ Stockholm, Dept Mat & Environm Chem, SE-10691 Stockholm, Sweden
关键词
THIN-FILMS; BATIO3; TUNABILITY; BEHAVIOR; VOLTAGE;
D O I
10.1063/1.3526375
中图分类号
O59 [应用物理学];
学科分类号
摘要
The nonlinear dielectric properties of dense BaTiO3 ceramics with grain size of 1 mu m-90 nm were investigated. In the finest ceramics, the permittivity reduces below 1000 and a remarkable nonhysteretic linear dc-tunability [epsilon(E)] is obtained at high field, above 40 kV/cm. The observed behavior was explained by considering the nanostructured ceramic as a composite formed by ferroelectric grains, whose nonlinearity is reducing, and by low-permittivity nonferroelectric grain boundaries, whose volume fraction increases when decreasing the grain size. Reducing the grain size in ferroelectric dense materials is an alternative route to accomplish the application requirements: nonhysteretic tunability and permittivity below 1000. (C) 2010 American Institute of Physics. [doi:10.1063/1.3526375]
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页数:3
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