Ru(IV)-catalyzed isomerization of allylamines in water:: A highly efficient procedure for the deprotection of N-allylic amines

被引：49

作者：

Cadierno, V ^{[1
]}

García-Garrido, SE ^{[1
]}

Gimeno, J ^{[1
]}

Nebra, N ^{[1
]}

机构：

[1] Univ Oviedo, CSIC, Inst Univ Quim Organomet Enrique Moles, Dept Quim Organ & Inorgan, E-33071 Oviedo, Spain

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 32期

关键词：

D O I：

10.1039/b506788j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general and efficient method for the deprotection of N-allylic substrates in aqueous media, using catalytic amounts of the bis(allyl)-ruthenium(IV) complexes [Ru(eta(3): eta(2):eta(3)-C12H18)Cl-2] (1) and [{Ru(eta(3):g(3)-C10H16)(mu-Cl)Cl}(2)] (2), has been developed.

引用

页码：4086 / 4088

页数：3

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