Improved electrode performance of porous LiFePO4 using RuO2 as an oxidic nanoscale interconnect

被引:388
作者
Hu, Yong-Sheng
Guo, Yu-Guo
Dominko, Robert
Gaberscek, Miran
Jamnik, Janko
Maier, Joachim
机构
[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
[2] Natl Inst Chem, Ljubljana 1001, Slovenia
关键词
D O I
10.1002/adma.200700697
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By using nanometer-sized RuO2 to "metalize" tiny pores and even "repair" incomplete electronically conducting (carbon) networks in porous carbon-containing LiFePO4 (see figure), the kinetics and rate capability of the composite are significantly improved. The key lies in the bonding properties of RuO2, which enables good contact to both the oxidic storage material as well as the carbon structures used as current collector.
引用
收藏
页码:1963 / +
页数:5
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