Dicarbonyldi-μ-chloro-cis,cis-η4-1,5-cyclooctadienedirhodium(I)

被引：2

作者：

Abou Rida, M

Saikaili, J

Smith, AK

Thozet, A

机构：

[1] Ecole Super Chim Phys Elect Lyon, Lab Chim Organomet Surface, CNRS, UMR 9986, F-69616 Villeurbanne, France

[2] Lebanese Univ, Fac Sci 2, Fanar Beirut, Lebanon

[3] Univ Lyon 1, Cristallog Lab, F-69622 Villeurbanne, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2001年 / 57卷 / 04期

关键词：

D O I：

10.1107/S0108270100020035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, dicarbonyl-1 kappa C-2-di-mu -chloro-1:2 kappa Cl-4-[cis,-cis-2(eta (4))-1,5-cyclooctadiene]dirhodium(I), [Rh2Cl2(C8H12)-(CO)(2)], consists of a dichloro-bridged dimer of rhodium, with a non-bonded Rh . . . Rh distance of 3.284 (2) Angstrom. One Rh atom is coordinated to two carbonyl ligands, while the other Rh atom is coordinated to the cyclooctadiene moiety.

引用

页码：352 / 353

页数：2

共 10 条

[1]

BOEYENS JCA, 1986, S AFR J CHEM, V39, P229

[2] Synthesis and X-ray powder diffraction characterization of (OC)2RhCl2Rh(cod) (cod = cycloocta-1,4-diene) [J].

Corradi, E ;

Masciocchi, N ;

Palyi, G ;

Ugo, R ;

Vizi-Orosz, A ;

Zucchi, C ;

Sironi, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (24) :4651-4655

[3] STRUCTURE OF AND METAL-METAL BONDING IN RH(CO)2CL [J].

DAHL, LF ;

MARTELL, C ;

WAMPLER, DL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (07) :1761-&

[4] DI-MU-CHLORO-BIS[CIS,CIS-ETA(4)-1,5-CYCLOOCTADIENE)RHODIUM(I)] - A REDETERMINATION [J].

DERIDDER, DJA ;

IMHOFF, P .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 :1569-1572

[5] CRYSTAL STRUCTURE OF DIMER OF RHODIUM CHLORIDE 1,5-CYCLOOCTADIENE [J].

IBERS, JA ;

SNYDER, RG .

ACTA CRYSTALLOGRAPHICA, 1962, 15 (OCT) :923-&

[6]

Nonius, 1998, COLLECT

[7] Processing of X-ray diffraction data collected in oscillation mode [J].

Otwinowski, Z ;

Minor, W .

MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 :307-326

[8]

SHELDRICK GM, 1997, SHELXL97 SHELXS97 SH

[9]

Spek A., 1990, ACTA CRYSTALLOGR, V46

[10] STRUCTURE OF DI-MU-CHLORO-BIS(DICARBONYLRHODIUM(I)) [J].

WALZ, L ;

SCHEER, P .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :640-641

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