Squaramides: Bridging from Molecular Recognition to Bifunctional Organocatalysis

被引：656

作者：

Aleman, Jose ^{[1
]}

Parra, Alejandro ^{[3
,4
]}

Jiang, Hao ^{[2
]}

Jorgensen, Karl Anker ^{[2
]}

机构：

[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ Modulo 1, E-28049 Madrid, Spain

[2] Aarhus Univ, Dept Chem, Ctr Catalysis, DK-8000 Aarhus C, Denmark

[3] Harvard Univ, Lab Prof Andrew Myers, Cambridge, MA 02138 USA

[4] Univ Autonoma Madrid, E-28049 Madrid, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 25期

关键词：

asymmetric synthesis; bifunctional catalysts; molecular recognition; organocatalysis; ENANTIOSELECTIVE MICHAEL ADDITION; HYDROGEN-BONDING INTERACTIONS; CONJUGATE ADDITION; HENRY REACTION; ASYMMETRIC CATALYSIS; 1,3-DICARBONYL COMPOUNDS; CHIRAL SQUARAMIDES; DIPHENYL PHOSPHITE; THIOUREA CATALYST; NITROOLEFINS;

D O I：

10.1002/chem.201003694

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this minireview, squaramides are presented from their roots as artificial anion receptors in molecular recognition studies to their recent advances as powerful bifunctional hydrogen-bonding catalysts in asymmetric organocatalysis. The main features of the squaramido functionality and the direct comparison with the analogous ureas and thioureas are also discussed.

引用

页码：6890 / 6899

页数：10

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