Synthesis of a stable biphenyl-bis(carbene) and -bis(silylene) [M{(NCH2But)2C6H3-3,4}]2 (M = C or Si)

被引：46

作者：

Gehrhus, B ^{[1
]}

Hitchcock, PB ^{[1
]}

Lappert, MF ^{[1
]}

机构：

[1] Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 08期

关键词：

carbene; silylene;

D O I：

10.1002/zaac.200500005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the biphenyl derivative [S=C{(NCH2BU1)(2)-C6H3-3,4}](2) or [Cl2Si{(NCH2But)(2)C6H3-3,4}](2) with C8K afforded the new bis(carbene) 1 or the first bis(silylene) 2, respectively. The X-ray structure of 2 is presented.

引用

页码：1383 / 1386

页数：4

共 45 条

[1] Chelating bis-carbene rhodium(III) complexes in transfer hydrogenation of ketones and imines [J].

Albrecht, M ;

Crabtree, RH ;

Mata, J ;

Peris, E .

CHEMICAL COMMUNICATIONS, 2002, (01) :32-33

[2] Synthesis and characterization of a saddle-shaped nickel-carbene complex derived from an imidazolium-linked meta-cyclophane [J].

Baker, MV ;

Skelton, BW ;

White, AH ;

Williams, CC .

ORGANOMETALLICS, 2002, 21 (13) :2674-2678

[3] Palladium carbene complexes derived from imidazolium-linked ortho-cyclophanes [J].

Baker, MV ;

Skelton, BW ;

White, AH ;

Williams, CC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (02) :111-120

[4] Bidentate N-heterocyclic carbene complexes of Group 13 trihydrides and trihalides [J].

Baker, RJ ;

Cole, ML ;

Jones, C ;

Mahon, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, Royal Society of Chemistry (09) :1992-1996

[5]

Bertrand G, 1999, EUR J INORG CHEM, P1965

[6]

Boesveld WM, 1999, CHEM COMMUN, P755

[7] Synthesis of constrained-geometry chiral Di-N-heterocyclic carbene ligands and their silver(I) and palladium(II) complexes [J].

Bonnet, LG ;

Douthwaite, RE ;

Hodgson, R .

ORGANOMETALLICS, 2003, 22 (22) :4384-4386

[8] Stable carbenes [J].

Bourissou, D ;

Guerret, O ;

Gabbaï, FP ;

Bertrand, G .

CHEMICAL REVIEWS, 2000, 100 (01) :39-91

[9] 1,1′-(Pyridine-2,6-diyl)bis(3-benzyl-2,3-dihydro-1H-imidazol-2-ylidene), a new multidentate N-heterocyclic biscarbene and its silver(I) complex derivative, (vol 617, pg 395, 2000) [J].

Caballero, A ;

Díez-Barra, E ;

Jalón, FA ;

Merino, S ;

Rodríguez, AM ;

Tejeda, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 627 (02) :263-264

[10] Stable N-functionalised 'pincer' bis carbene ligands and their ruthenium complexes; synthesis and catalytic studies [J].

Danopoulos, AA ;

Winston, S ;

Motherwell, WB .

CHEMICAL COMMUNICATIONS, 2002, (13) :1376-1377

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