Complete diastereofacial selective cycloaddition of new sulfinyl dienophiles (Ss)-and (Rs)-(-)menthyl alpha-(2-methoxyphenylsulfoxyl)acylate with anthracene under chelation control

被引：5

作者：

Chau, TY ^{[1
]}

Lin, HC ^{[1
]}

Hu, WH ^{[1
]}

机构：

[1] CHENGDU INST ORGAN CHEM, UNION LAB ASYMMETR SYNTH, CHENGDU 610041, PEOPLES R CHINA

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 10期

关键词：

D O I：

10.1080/00397919608003539

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New sulfinyldienophiles (Ss)- and (Rs)- (-)menthyl alpha-(2-methoxyphenylsulfoxyl)acylate were prepared. Cycloadditions with anthracene in dichloromethane proceeded with complete diastereoselectivity under chelation control. Chirality at sulfur controlled diastereofacial selectivity.

引用

页码：1867 / 1874

页数：8

共 10 条

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