Selective and effective functionalization of alkanes and cycloalkanes with CO by polyhalomethanes combined with aluminum halides in organic media

被引：7

作者：

Akhrem, I ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

TOPICS IN CATALYSIS | 1998年 / 6卷 / 1-4期

关键词：

alkanes; cycloalkanes; organosilanes; superacids; carbon monoxide; complexes of polyhalomethanes with aluminum halides; carbonylation;

D O I：

10.1023/A:1019110305311

中图分类号：

O69 [应用化学];

学科分类号：

081704 [应用化学];

摘要：

Effective and selective transformations of propane, butane, cyclopentane, cyclohexane, methylcyclopentane and adamantane under the action of CO mediated by polyhalomethanes combined with aluminum halides (in the presence of hydride or alkyl (aryl) group donors or without them) resulting in esters, ketones and aldehydes are summarized.

引用

页码：27 / 39

页数：13

共 85 条

[1]

An effective formylation of adamantane with CO initiated by the aprotic organic superacid CBr4 center dot 2AlBr(3) under mild conditions [J].

Akhrem, I ;

Churilova, I ;

Bernadyuk, S ;

Volpin, M .

TETRAHEDRON LETTERS, 1996, 37 (32) :5775-5778

[2]

A NOVEL FAMILY OF APROTIC ORGANIC SUPERACIDS FOR LOW-TEMPERATURE ALKANE AND CYCLOALKANE TRANSFORMATIONS [J].

AKHREM, I ;

ORLINKOV, A ;

VOLPIN, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) :671-672

[3]

Novel sulfur-containing inorganic aprotic superacids as effective initiators of low-temperature cracking and isomerization of alkanes [J].

Akhrem, I ;

Gudima, S ;

Volpin, M .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (07) :812-814

[4]

Akhrem I. S., 1996, RUSS CHEM REV, V65, P849

[5]

Functionalization of saturated hydrocarbons by aprotic superacids .6. Effective regioselective monoformylation of adamantane in the presence of a hydride ion donor [J].

Akhrem, IS ;

Churilova, IM ;

Vitt, SV ;

Orlinkov, AV ;

Volpin, ME .

RUSSIAN CHEMICAL BULLETIN, 1997, 46 (03) :491-495

[6]

Functionalization of saturated hydrocarbons by aprotic superacids .5. Regioselective carbonylation of propane in an organic solvent initiated by aprotic organic superacids CX(4)center dot nAlBr(3) (X=Br,Cl; n=1 or 2) [J].

Akhrem, IS ;

Orlinkov, AV ;

Afanaseva, LV ;

Volpin, ME .

RUSSIAN CHEMICAL BULLETIN, 1996, 45 (05) :1154-1156

[7]

AKHREM IS, 1993, MENDELEEV COMMUN, P188

[8]

NATURE OF THE SPECIES RESPONSIBLE FOR THE HIGH-ACTIVITY OF RCOX.2ALX3 COMPLEXES IN REACTIONS WITH ALKANES AND CYCLOALKANES [J].

AKHREM, IS ;

ORLINKOV, AV ;

BAKHMUTOV, VI ;

AFANASEVA, LV ;

VOLPIN, ME .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (11) :2252-2256

[9]

Polyhalomethanes combined with aluminum halides as generators of superelectrophiles of a novel type [J].

Akhrem, IS ;

Chistyakov, AL ;

Gambaryan, NP ;

Stankevich, IV ;

Volpin, ME .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 536 (1-2) :489-495

[10]

TRANSFORMATIONS OF CYCLOALKANES UNDER THE ACTION OF ACYL HALIDES IN THE PRESENCE OF AIBR3 [J].

AKHREM, IS ;

ORLINKOV, AV ;

MYSOV, EI ;

VOLPIN, ME .

TETRAHEDRON LETTERS, 1981, 22 (39) :3891-3894

← 1 2 3 4 5 6 7 8 9 →