Metallo-supramolecular polymers based on functionalized bis-terpyridines as novel electrochromic materials

被引：224

作者：

Han, Fu She

Higuchi, Masayoshi

Kurth, Dirk G.

机构：

[1] Natl Inst Mat Sci, Organ Nanomat Ctr, Funct Modules Grp, Tsukuba, Ibaraki 3050044, Japan

[2] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

来源：

ADVANCED MATERIALS | 2007年 / 19卷 / 22期

关键词：

D O I：

10.1002/adma.200700931

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembly of various metallo-supra-molecular coordination polyelectrolytes (MEPEs) based on pyridine ring functionalized ditopic bis-terpyridines, 2 as well as the electrochromic property is presented. MEPEs derived from electron-donating OMe functionalized ligands exhibit rapid switching rates, good reversibility, high stability, and an optical memory. The first structure-property relationships are proposed, which are needed for the de novo design and fabrication of new materials.

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页码：3928 / +

页数：5

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