Combinatorial synthesis of metal-organic frameworks libraries by click-chemistry

被引：44

作者：

Savonnet, Marie ^{[1
,2
]}

Kockrick, Emanuel ^{[1
]}

Camarata, Aurelie ^{[1
]}

Bazer-Bachi, Delphine ^{[2
]}

Bats, Nicolas ^{[2
]}

Lecocq, Vincent ^{[2
]}

Pinel, Catherine ^{[1
]}

Farrusseng, David ^{[1
]}

机构：

[1] Univ Lyon, IRCELYON, CNRS, F-69626 Villeurbanne, France

[2] IFP Energies Nouvelles, Catalysis & Separat Div, F-69360 Solaize, France

来源：

NEW JOURNAL OF CHEMISTRY | 2011年 / 35卷 / 09期

关键词：

ZEOLITIC IMIDAZOLATE FRAMEWORKS; POSTSYNTHETIC MODIFICATION; COVALENT MODIFICATION; BUILDING UNITS; HYDROGENATION; DESIGN; COMPLEXES; SOLIDS; ENANTIOSELECTIVITY; CATALYSTS;

D O I：

10.1039/c1nj20350a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A key to address advanced MOF materials suitable for more sophisticated applications is to add functionalities of greater complexity in a controlled manner. We report a generic and original post-synthetic modification method starting from amino derived MOFs. The first step consists in converting the amino group into azide (N-3). Without isolation nor purification, the desired functionalized material is obtained by grafting the corresponding alkyne using "Click Chemistry''. This work reports for the first time the synthesis of a two-dimensional combinatorial library of 24 functionalized MOFs. We also show that the grafting yield can be controlled from 10 to 100%. Finally, we compare the effect of the grafting yield on the porous volume of (1D) and (3D)MOF porous structures.

引用

页码：1892 / 1897

页数：6

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