Bismuth(III) chloride-catalyzed direct deoxygenative allylation of substituted benzylic alcohols with allyltrimethylsilane

被引:65
作者
De, SK [1 ]
Gibbs, RA
机构
[1] Purdue Univ, Sch Pharm, Dept Med Chem & Mol Pharmacol, W Lafayette, IN 47907 USA
[2] Purdue Univ, Purdue Canc Ctr, W Lafayette, IN 47907 USA
关键词
bismuth(III) chloride; alcohols; allyltrimethylsilane; allylation;
D O I
10.1016/j.tetlet.2005.09.161
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A highly-effective protocol for allylation of sec-benzyl alcohols with allyltrimethylsilane in the presence of a catalytic amount of bismuth(III) chloride has been developed. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8345 / 8350
页数:6
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