Novel vanadium-catalyzed oxidation of alcohols to aldehydes and ketones under atmospheric oxygen

被引：193

作者：

Velusamy, S ^{[1
]}

Punniyamurthy, T ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Gauhati 781039, India

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 02期

关键词：

D O I：

10.1021/ol036166x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Oxidation of alcohols to aldehydes and ketones has been studied in high yields using atmospheric oxygen and a catalytic amount Of V2O5 in toluene under heating (ca. 100 degreesC). Secondary alcohols can be chemoselectively converted into ketones in the presence of primary hydroxy groups.

引用

页码：217 / 219

页数：3

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