Enzymatic reductions for the chemist

被引：351

作者：

Hollmann, Frank ^{[1
]}

Arends, Isabel W. C. E. ^{[1
]}

Holtmann, Dirk ^{[2
]}

机构：

[1] Delft Univ Technol, Dept Biotechnol, NL-2628 BL Delft, Netherlands

[2] DECHEMA eV, Karl Winnacker Inst, D-60486 Frankfurt, Germany

来源：

GREEN CHEMISTRY | 2011年 / 13卷 / 09期

关键词：

OLD YELLOW ENZYME; PENTAERYTHRITOL TETRANITRATE REDUCTASE; SECONDARY ALCOHOL-DEHYDROGENASE; SUPERCRITICAL CARBON-DIOXIDE; RECOMBINANT ESCHERICHIA-COLI; ASYMMETRIC HYDROGEN-TRANSFER; WHOLE-CELL-CATALYST; ENANTIOSELECTIVE MICROBIAL REDUCTION; HIGHLY STEREOSELECTIVE REDUCTION; ARTIFICIAL TRANSFER HYDROGENASES;

D O I：

10.1039/c1gc15424a

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

When challenged by a difficult reduction reaction, a chemist should always also consider biocatalysis in synthesis planning. The inherent selectivity of enzymes has been known for many decades now and the practical applicability of biocatalysis has undergone dramatic improvements rendering it a true alternative to established chemocatalysis. In this contribution recent developments in the field of enzymatic reduction using whole cells and isolated enzymes are reviewed.

引用

收藏

页码：2285 / 2314

页数：30

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