Advances in the chemical modification of epitaxial graphene

被引：102

作者：

Bekyarova, E. ^{[1
,2
]}

Sarkar, S. ^{[1
,2
]}

Niyogi, S. ^{[1
,2
]}

Itkis, M. E. ^{[1
,2
]}

Haddon, R. C. ^{[1
,2
,3
]}

机构：

[1] Univ Calif Riverside, Ctr Nanoscale Sci & Engn, Riverside, CA 92521 USA

[2] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[3] Univ Calif Riverside, Dept Chem & Environm Engn, Riverside, CA 92521 USA

来源：

JOURNAL OF PHYSICS D-APPLIED PHYSICS | 2012年 / 45卷 / 15期

基金：

美国国家科学基金会;

关键词：

SCANNING-TUNNELING-MICROSCOPY; ORIENTED PYROLYTIC-GRAPHITE; WALLED CARBON NANOTUBES; CLUSTER MODEL APPROACH; DIELS-ALDER REACTION; ELECTROCHEMICAL REDUCTION; DIAZONIUM SALTS; REVERSIBLE HYDROGENATION; COVALENT MODIFICATION; RAMAN-SPECTROSCOPY;

D O I：

10.1088/0022-3727/45/15/154009

中图分类号：

O59 [应用物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Chemistry will play an increasingly important role in the realization of graphene applications. The chemical formation of covalent carbon-carbon bonds involving the basal plane carbon atoms offers an alternative approach to the control of the electronic properties of graphene, and potentially allows the generation of insulating and semiconducting regions in graphene wafers. This review summarizes recent progress in the covalent modification of epitaxial graphene and the effect that chemistry has on the electronic and magnetic properties of the material.

引用

页数：18

共 117 条

[1]

Covalent modification of carbon surfaces by aryl radicals generated from the electrochemical reduction of diazonium salts [J].