Copper(II) complexes of unsymmetric compartmental ligands bearing adjacent {N2O}, {N,S,O} donor sets and {N2O}, {N,O} donor sets

被引:12
作者
Adams, H [1 ]
Clunas, S [1 ]
Cummings, LR [1 ]
Fenton, DE [1 ]
McHugh, PE [1 ]
机构
[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
基金
英国工程与自然科学研究理事会;
关键词
crystal structure; dinuclear copper(II) complexes;
D O I
10.1016/S1387-7003(03)00118-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The unsymmetric compartmental proligands HL2, HL5 and HL6 bearing adjacent {N2O}, {N,S,O} donor sets and {N2O}, {N,O} donor sets have given the dinuclear copper (II) complexes [Cu-2(L-2) (OMe)(NCS)(2)], 1, [Cu-2(L-5)(OMe)(NCS)(2)], 2, and [Cu-2(L-6)(OMe)(NCS)(2)], 3. The crystal structures of these complexes are reported. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:837 / 840
页数:4
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