Reductive cleavage and related reactions leading to molybdenum-element multiple bonds: new pathways offered by three-coordinate molybdenum(III)

被引：168

作者：

Cummins, CC ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 17期

关键词：

D O I：

10.1039/a802402b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three-coordinate molybdenum(III) complexes comprise a new class of reactive-yet-isolable substances. Related to a well known class of metal-metal triple bonded dimers, the monomeric molybdenum(III) complexes supported by sterically-demanding N-tert-alkylanilide ligands offer previously unavailable synthetic routes to molybdenum-element multiple bonds. Terminal nitride, phosphide and carbide functionalities have been prepared from reactions with dinitrogen, white phosphorus and carbon monoxide, respectively.

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页码：1777 / 1786

页数：10

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