Isotope effects in the chemistry of atmospheric trace compounds

被引：156

作者：

Brenninkmeijer, CAM ^{[1
]}

Janssen, C

Kaiser, J

Röckmann, T

Rhee, TS

Assonov, SS

机构：

[1] Max Planck Inst Chem, D-55128 Mainz, Germany

[2] Princeton Univ, Dept Geosci, Princeton, NJ 08544 USA

[3] Max Planck Inst Nucl Phys, D-69117 Heidelberg, Germany

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 12期

关键词：

D O I：

10.1021/cr020644k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The isotope effects in the chemistry of atmospheric trace compounds were discussed. It was found that isotope effects fractionate the trace gas remaining in the atmosphere and fall within the class of kinetic isotope effects. It was observed that most sink processes caused isotopic changes and the remaining unreacted trace gas gradually acquired a different isotopic composition. The isotopic analysis of 15N and 18O of nitrate was also elaborated.

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页码：5125 / 5161

页数：37

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