Oxidation of organic substrates catalyzed by a novel mixed-ligand [RuIII(app) (pic) (H2O)]+ complex

被引：16

作者：

Chatterjee, D ^{[1
]}

Mitra, A ^{[1
]}

机构：

[1] Cent Mech Engn Res Inst, Chem Sect, Durgapur 713209, India

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 11期

关键词：

oxo transfer catalysis; ruthenium complex; t-BuOOH; cyclohexene; cyclohexane;

D O I：

10.1016/S1387-7003(00)00145-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Cationic [Ru-III(app)(pic)(H2O)](+) (1) complex (Happ = N-(hydroxyphenyl)pyridine-2-carboxaldimine; Hpic = picolinic acid) has been synthesized and characterized by physico-chemical methods and employed as catalyst in the oxidation of both saturated and unsaturated hydrocarbons using tert-butylhydroperoxide (t-BuOOH). A mechanism involving formation of and transfer from a reactive high valent Ru(V)-oxo species as catalytic intermediate is proposed for the catalytic processes. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：640 / 644

页数：5

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