Crystal facet engineering of semiconductor photocatalysts: motivations, advances and unique properties

被引：891

作者：

Liu, Gang ^{[4
]}

Yu, Jimmy C. ^{[1
,2
]}

Lu, Gao Qing ^{[3
]}

Cheng, Hui-Ming ^{[4
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

[2] Chinese Univ Hong Kong, Inst Environm Energy & Sustainabil, Shatin, Hong Kong, Peoples R China

[3] Univ Queensland, ARC Ctr Excellence Funct Nanomat, Brisbane, Qld 4072, Australia

[4] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 24期

关键词：

SHAPE-CONTROLLED SYNTHESIS; RUTILE TIO2 NANORODS; SOLVENT-SOLUTE INTERACTIONS; LOW-TEMPERATURE SYNTHESIS; ORDERED SOLID-PHASES; EXPOSED; 001; FACETS; PLATINUM NANOCRYSTALS; HYDROGEN-PRODUCTION; TITANIUM-DIOXIDE; HIERARCHICAL SPHERES;

D O I：

10.1039/c1cc10665a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal facet engineering of semiconductors has become an important strategy for fine-tuning the physicochemical properties and thus optimizing the reactivity and selectivity of photocatalysts. In this review, we present the basic strategies for crystal facet engineering of photocatalysts and describe the recent advances in synthesizing faceted photocatalysts, in particular TiO2 crystals. The unique properties of faceted photocatalysts are discussed in relation to anisotropic corrosion, interaction dependence of adsorbates, photocatalytic selectivity, photo-reduction and oxidation sites, and photocatalytic reaction order. Ideas for future research on crystal facet engineering for improving the performance of photocatalysts are also proposed.

引用

页码：6763 / 6783

页数：21

共 214 条

[11] Direct visualization of defect-mediated dissociation of water on TiO2(110) [J].

Bikondoa, O ;

Pang, CL ;

Ithnin, R ;

Muryn, CA ;

Onishi, H ;

Thornton, G .

NATURE MATERIALS, 2006, 5 (03) :189-192

[12] ROLE OF SOLVENT-SOLUTE INTERACTIONS IN DETERMINING CRYSTAL-GROWTH MECHANISMS FROM SOLUTION .1. SURFACE ENTROPY FACTOR [J].

BOURNE, JR ;

DAVEY, RJ .

JOURNAL OF CRYSTAL GROWTH, 1976, 36 (02) :278-286

[13] ROLE OF SOLVENT-SOLUTE INTERACTIONS IN DETERMINING CRYSTAL-GROWTH MECHANISMS FROM SOLUTION .2. GROWTH KINETICS OF HEXAMETHYLENE TETRAMINE [J].

BOURNE, JR ;

DAVEY, RJ .

JOURNAL OF CRYSTAL GROWTH, 1976, 36 (02) :287-296

[14] Nonhydrolytic synthesis of high-quality anisotropically shaped brookite TiO2 nanocrystals [J].

Buonsanti, Raffaella ;

Grillo, Vincenzo ;

Carlino, Elvio ;

Giannini, Cinzia ;

Kipp, Tobias ;

Cingolani, Roberto ;

Cozzoli, Pantaleo Davide .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :11223-11233

[15] Chemistry and properties of nanocrystals of different shapes [J].

Burda, C ;

Chen, XB ;

Narayanan, R ;

El-Sayed, MA .

CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102

[16] Shape-selective photocatalytic transformation of phenols in an aqueous medium [J].

Calza, P ;

Pazé, C ;

Pelizzetti, E ;

Zecchina, A .

CHEMICAL COMMUNICATIONS, 2001, (20) :2130-2131

[17]

Chemseddine A, 1999, EUR J INORG CHEM, P235, DOI 10.1002/(SICI)1099-0682(19990202)1999:2<235::AID-EJIC235>3.0.CO

[18]

2-N

[19] Quantum Dot Monolayer Sensitized ZnO Nanowire-Array Photoelectrodes: True Efficiency for Water Splitting [J].

Chen, Hao Ming ;

Chen, Chih Kai ;

Chang, Yu-Chuan ;

Tsai, Chi-Wen ;

Liu, Ru-Shi ;

Hu, Shu-Fen ;

Chang, Wen-Sheng ;

Chen, Kuei-Hsien .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (34) :5966-5969

[20] Shape-controlled synthesis of platinum nanocrystals for catalytic and electrocatalytic applications [J].

Chen, Jingyi ;

Lim, Byungkwon ;

Lee, Eric P. ;

Xia, Younan .

NANO TODAY, 2009, 4 (01) :81-95

← 1 2 3 4 5 6 7 8 9 10 →