Crystal facet engineering of semiconductor photocatalysts: motivations, advances and unique properties

被引：891

作者：

Liu, Gang ^{[4
]}

Yu, Jimmy C. ^{[1
,2
]}

Lu, Gao Qing ^{[3
]}

Cheng, Hui-Ming ^{[4
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

[2] Chinese Univ Hong Kong, Inst Environm Energy & Sustainabil, Shatin, Hong Kong, Peoples R China

[3] Univ Queensland, ARC Ctr Excellence Funct Nanomat, Brisbane, Qld 4072, Australia

[4] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 24期

关键词：

SHAPE-CONTROLLED SYNTHESIS; RUTILE TIO2 NANORODS; SOLVENT-SOLUTE INTERACTIONS; LOW-TEMPERATURE SYNTHESIS; ORDERED SOLID-PHASES; EXPOSED; 001; FACETS; PLATINUM NANOCRYSTALS; HYDROGEN-PRODUCTION; TITANIUM-DIOXIDE; HIERARCHICAL SPHERES;

D O I：

10.1039/c1cc10665a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal facet engineering of semiconductors has become an important strategy for fine-tuning the physicochemical properties and thus optimizing the reactivity and selectivity of photocatalysts. In this review, we present the basic strategies for crystal facet engineering of photocatalysts and describe the recent advances in synthesizing faceted photocatalysts, in particular TiO2 crystals. The unique properties of faceted photocatalysts are discussed in relation to anisotropic corrosion, interaction dependence of adsorbates, photocatalytic selectivity, photo-reduction and oxidation sites, and photocatalytic reaction order. Ideas for future research on crystal facet engineering for improving the performance of photocatalysts are also proposed.

引用

页码：6763 / 6783

页数：21

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