Chromatographic determination of phenylarsenic compounds

被引：64

作者：

Haas, R

Schmidt, TC

Steinbach, K

von Low, E

机构：

[1] Buro Altlastenerkundung & Umweltforsch, D-35037 Marburg, Germany

[2] Philipps Univ Marburg, Med Ctr Hyg, D-35037 Marburg, Germany

[3] Univ Marburg, Dept Chem, D-35032 Marburg, Germany

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1998年 / 361卷 / 03期

关键词：

D O I：

10.1007/s002160050892

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Gas chromatographic (GC) and liquid chromatographic methods for the investigation of phenylarsenic compounds are presented. With gas chromatography using an electron capture detector (ECD), the chemical warfare agents PFIFFIKUS, CLARK I and CLARK II can be detected. After derivatization with mercaptans and dimercaptans the sum of diphenylarsenic compounds resp. phenylarsenic and phenylarsonic compounds can be detected as the mercapto reap. dimercapto derivatives. High performance liquid chromatography (HPLC) analysis may be used for the detection of triphenylarsenic compounds and ADAMSITE.

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收藏

页码：313 / 318

页数：6

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