The first PdII complex of a non-heteroatom stabilised carbene ligand

被引:79
作者
Bröring, M [1 ]
Brandt, CD [1 ]
Stellwag, S [1 ]
机构
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
关键词
D O I
10.1039/b307160j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Di(p-tolyl)diazomethane reacts with the tripyrrinate Trpy-PdOAcF 1 after activation with NaBArF to yield the first stable Pd-II complex 2 of a non-Arduengo, type carbene ligand, which could be characterised by X-ray crystallography.
引用
收藏
页码:2344 / 2345
页数:2
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