Anion-arene adducts:: C-H hydrogen bonding, anion-π interaction, and carbon bonding motifs

被引：355

作者：

Hay, Benjamin P. ^{[1
]}

Bryantsev, Vyacheslav S. ^{[2
]}

机构：

[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[2] CALTECH, Mat & Proc Simulat Ctr, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 21期

关键词：

D O I：

10.1039/b800055g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This article summarizes experimental and theoretical evidence for the existence of four distinct binding modes for complexes of anions with charge-neutral arenes. These include C-H hydrogen bonding and three motifs involving the arene-pi system-the noncovalent anion-pi interaction, weakly covalent sigma interaction, and strongly covalent sigma interaction.

引用

页码：2417 / 2428

页数：12

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