Anion-arene adducts:: C-H hydrogen bonding, anion-π interaction, and carbon bonding motifs

被引：355

作者：

Hay, Benjamin P. ^{[1
]}

Bryantsev, Vyacheslav S. ^{[2
]}

机构：

[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[2] CALTECH, Mat & Proc Simulat Ctr, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 21期

关键词：

D O I：

10.1039/b800055g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This article summarizes experimental and theoretical evidence for the existence of four distinct binding modes for complexes of anions with charge-neutral arenes. These include C-H hydrogen bonding and three motifs involving the arene-pi system-the noncovalent anion-pi interaction, weakly covalent sigma interaction, and strongly covalent sigma interaction.

引用

页码：2417 / 2428

页数：12

共 111 条

[51] Crystallographic evidence for oxygen acceptor directionality in oxyanion hydrogen bonds [J].

Hay, BP ;

Dixon, DA ;

Bryan, JC ;

Moyer, BA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (02) :182-183

[52] Towards the design of neutral molecular tweezers for anion recognition [J].

Hermida-Ramon, Jose M. ;

Estevez, Carlos M. .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (17) :4743-4749

[53] A DETERMINATION OF THE STABILITIES AND STRUCTURES OF F-(C6H6) AND F-(C6F6) CLUSTERS [J].

HIRAOKA, K ;

MIZUSE, S ;

YAMABE, S .

JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (07) :4102-4105

[54] HIGH-SYMMETRICAL STRUCTURE OF THE GAS-PHASE CLUSTER IONS X-...C6F6(X = CL, BR, AND I) [J].

HIRAOKA, K ;

MIZUSE, S ;

YAMABE, S .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (20) :5294-5297

[55] DETERMINATION OF THE STABILITIES AND STRUCTURES OF CL-(C6H6), BR-(C6H6), I-(C6H6) CLUSTERS [J].

HIRAOKA, K ;

MIZUSE, S ;

YAMABE, S .

CHEMICAL PHYSICS LETTERS, 1988, 147 (2-3) :174-178

[56] A new antimetabolite, 5-morpholinomethyl-2-thiouracil - spectral properties, thermal profiles, antibacterial, antifungal and antitumour studies of some of its metal chelates [J].

Kamalakannan, P ;

Venkappayya, D ;

Balasubramanian, T .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (17) :3381-3391

[57] ELECTRON-AFFINITIES AND ELECTRON-TRANSFER REACTIONS [J].

KEBARLE, P ;

CHOWDHURY, S .

CHEMICAL REVIEWS, 1987, 87 (03) :513-534

[58] ELECTRON-AFFINITIES OF THE 1ST-ROW ATOMS REVISITED - SYSTEMATIC BASIS-SETS AND WAVE-FUNCTIONS [J].

KENDALL, RA ;

DUNNING, TH ;

HARRISON, RJ .

JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (09) :6796-6806

[59] Theoretical investigations of anion-π interactions:: The role of anions and the nature of π systems [J].

Kim, D ;

Tarakeshwar, P ;

Kim, KS .

JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (07) :1250-1258

[60] Formation and properties of cyclo[6]pyrrole and cyclo[7]pyrrole [J].

Köhler, T ;

Seidel, D ;

Lynch, V ;

Arp, FO ;

Ou, ZP ;

Kadish, KM ;

Sessler, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (23) :6872-6873

← 1 2 3 4 5 6 7 8 9 10 →