Bowl-to-bowl inversion of sumanene derivatives

被引：117

作者：

Amaya, Toru ^{[1
]}

Sakane, Hiroyuki ^{[1
]}

Muneishi, Toshiko ^{[1
]}

Hirao, Toshikazu ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 06期

关键词：

D O I：

10.1039/b712839h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bowl-to-bowl inversion of the non-planar bowl-shaped compounds derived from sumanene as a fullerene C-3v fragment was found to be slow and tuned by a solvent, and the benzylic mono- and di-anions inverted even more slowly.

引用

页码：765 / 767

页数：3

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