The asymmetric intramolecular Heck reaction in natural product total synthesis

被引：1392

作者：

Dounay, AB ^{[1
]}

Overman, LE ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 08期

关键词：

D O I：

10.1021/cr020039h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three major factors contribute to the broad utility of catalytic asymmetric Heck cyclizations in the construction of complex structures. It is certain that many more applications of catalytic asymmetric intramolecular Heck reactions will be described. As such, some use is found in the small number of ligands, with Noyori's BINAP ligand being the most widely employed.

引用

页码：2945 / 2963

页数：19

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