Intermetallic compounds formed at the interface between Cu substrate and an Sn-9Zn-0.5Ag lead-free solder

被引:13
作者
Chang, TC
Hon, MH
Wang, MC
机构
[1] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 70101, Taiwan
[2] Natl Kaohsiung Univ Appl Sci, Dept Mech Engn, Kaohsiung 80782, Taiwan
关键词
intermetallic compounds; alloy; X-ray diffraction; interface;
D O I
10.1016/S0025-5408(03)00024-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The intermetallic compounds (IMCs) formed at the interface between Cu substrate and an Sn-9Zn-0.5Ag lead-free solder alloy have been investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM) and electron diffraction (ED). The XRD patterns show that the main IMCs formed at the interface of Sn-9Zn-0.5Ag/Cu are gamma-Cu5Zn8 and eta'-Cu6Sn5. The Ag3Sn IMC with orthorhombic structure was also observed at the Sn-9Zn-0.5Ag/Cu interface by TEM and ED analyses. The interfacial adhesion strength between the Cu substrate and Sn-9Zn-0.5Ag lead-free solder alloy is higher than that of the Sn-9Zn alloy due to the formation of Ag3Sn IMC at the interface. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:909 / 916
页数:8
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