Application of multivariate techniques in optimization of spectroanalytical methods

被引:87
作者
Ferreira, Sergio Luis Costa [1 ]
Andrade Korn, Maria das Gracas
Ferreira, Hadla Sousa
da Silva, Erik Galvao Paranhos
Araujo, Rennan Geovanny Oliveira
Souza, Anderson Santos
Macedo, Samuel Marques
de Castro Lima, Daniel
de Jesus, Raildo Mota
Amorim, Fabio Alan Carqueija
Bosque-Sendra, Juan Manuel
机构
[1] Univ Fed Bahia, Inst Quim, Salvador, BA, Brazil
[2] Univ Fed Bahia, Inst Ciencias Ambientais & Desenvolvimento S, Barreiras, BA, Brazil
[3] Univ Granada, Fac Sci, Dept Analyt Chem, Granada, Spain
关键词
multivariate techniques; factorial design; central composite design; Doehlert matrix; Box-Behnken design; AAS; ICP; spectroanalytical methods;
D O I
10.1080/05704920701551506
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
The present article describes fundamentals and applications of multivariate techniques used for the optimization of analytical procedures and systems involving spectroanalytical methods such as flame atomic absorption spectrometry (FAAS), electrothermal atomic absorption spectrometry (ETAAS), inductively coupled plasma optical emission spectrometry (ICP OES), and inductively coupled plasma mass spectrometry (ICP-MS), considering the main steps of a chemical analysis. This way, applications of experimental designs in optimization of sampling systems, digestion procedures, preconcentration procedures, instrumental parameters of quantification steps of analytical methods, and robustness tests have been summarized in this work.
引用
收藏
页码:475 / 491
页数:17
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