First example of hydrolytic kinetic resolution of acrylate of secondary alcohols by lipase Amano AK

被引：8

作者：

Bora, Pranjal P. ^{[1
]}

Bez, Ghanashyam ^{[1
]}

Anal, Jasha Momo H. ^{[1
]}

机构：

[1] NE Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India

来源：

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC | 2011年 / 72卷 / 3-4期

关键词：

Lipase; Alcohol; Acrylates; Enantioselective; Aqueous; CATALYZED TRANSESTERIFICATION; ENANTIOSELECTIVE SYNTHESIS; INDUSTRIAL BIOCATALYSIS; COMBINATION; ENANTIOMER; TRENDS;

D O I：

10.1016/j.molcatb.2011.06.015

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

070307 [化学生物学]; 071010 [生物化学与分子生物学];

摘要：

Lipase Amano AK is found to be extremely efficient catalyst for hydrolytic kinetic resolution of acrylates of secondary alcohols in aqueous phosphate buffer at pH 7.0. Both aliphatic and benzylic secondary alcohols show good to excellent E values. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：270 / 275

页数：6

共 35 条

[1]

Biocatalysis applied to the synthesis of agrochemicals [J].

Aleu, J. ;

Bustillo, A. J. ;

Hernandez-Galan, R. ;

Collado, I. G. .

CURRENT ORGANIC CHEMISTRY, 2006, 10 (16) :2037-2054

[2]

Lipase-catalyzed transesterification of primary alcohols: resolution of 2-ethylhexan-1-ol and 2-ethylhex-5-en-1-ol [J].

Baczko, K ;

Larpent, C .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2000, (03) :521-526

[3]

Highly enantioselective aminoacylase-catalyzed transesterification of secondary alcohols [J].

Bakker, M ;

Spruijt, AS ;

van Rantwijk, F ;

Sheldon, RA .

TETRAHEDRON-ASYMMETRY, 2000, 11 (08) :1801-1808

[4]

Stereoselective total synthesis of (+)-boronolide [J].

Boruwa, J ;

Barua, NC .

TETRAHEDRON, 2006, 62 (06) :1193-1198

[5]

Enantioselective reduction of ketones with NaBH4/diglyme possibly catalysed by trialkyl borate:: optically active sec-alcohols from prochiral ketones with catalytic (-)-menthol:: autocatalysis option [J].

Chandrasekhar, S ;

Hota, R .

TETRAHEDRON-ASYMMETRY, 2005, 16 (04) :751-754

[6]

Lipase-mediated enantioselective acylation of alcohols with functionalized vinyl esters: acyl donor tolerance and applications [J].

Chenevert, Robert ;

Pelchat, Nicholas ;

Morin, Pierre .

TETRAHEDRON-ASYMMETRY, 2009, 20 (10) :1191-1196

[7]

Chemoenzymatic synthesis of optically active γ-alkyl-γ-butenolides [J].

Fujii, Mikio ;

Fukumura, Motonori ;

Hori, Yumiko ;

Hirai, Yasuaki ;

Akita, Hiroyuki ;

Nakamura, Kaoru ;

Toriizuka, Kazuo ;

Ida, Yoshiteru .

TETRAHEDRON-ASYMMETRY, 2006, 17 (15) :2292-2298

[8]

Fürstner A, 2000, ANGEW CHEM INT EDIT, V39, P3012

[9]

Exploiting the reversibility of olefin metathesis.: Syntheses of macrocyclic trisubstituted alkenes and (R,R)-(-)-pyrenophorin [J].

Fürstner, A ;

Thiel, OR ;

Ackermann, L .

ORGANIC LETTERS, 2001, 3 (03) :449-451

[10]

Trends in lipase-catalyzed asymmetric access to enantiomerically pure/enriched compounds [J].

Ghanem, Ashraf .

TETRAHEDRON, 2007, 63 (08) :1721-1754

← 1 2 3 4 →