Cu(II)- and Hg(II)-induced modulation of the fluorescence behavior of a redox-active sensor molecule

被引：122

作者：

Hennrich, G

Walther, W

Resch-Genger, U

Sonnenschein, H

机构：

[1] Fed Inst Mat Res & Testing, D-12489 Berlin, Germany

[2] Inst Nonclass Chem, D-04303 Leipzig, Germany

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 04期

关键词：

D O I：

10.1021/ic000827u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Here, we report on a fluorescent 1,2,4-thiadiazole derivative (oxidized form) and its reduced form, the corresponding iminoyl thiourea. The thiadiazole displays a strong modulation of its fluorescence behavior, selectively upon addition of Cu(II), while the iminoyl thiourea functions as a chemodosimeter for Hg(II). Additionally, the Cu(II)-thiadiazole complex is characterized by HRMS, and the HE(II)-induced desulfurization of the iminoyl thiourea is monitored by mass spectrometry.

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页码：641 / 644

页数：4

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共 42 条

[1] Synthesis, structure, and ion selective complexation of trans and cis isomers of photochromic dithia-18-crown-6 ethers [J].

Alfimov, MV ;

Gromov, SP ;

Fedorov, YV ;

Fedorova, OA ;

Vedernikov, AI ;

Churakov, AV ;

Kuz'mina, LG ;

Howard, JAK ;

Bossmann, S ;

Braun, A ;

Woerner, M ;

Sears, DF ;

Saltiel, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (21) :4992-5000

[2]

Amendola V, 1999, CHEM-EUR J, V5, P3679, DOI 10.1002/(SICI)1521-3765(19991203)5:12<3679::AID-CHEM3679>3.0.CO

[3]

2-J

[4] Photochemical investigations of functionalised 1,4,7,10-tetraazacyclododecane ligands incorporating naphthyl chromophores [J].

Beeby, A ;

Parker, D ;

Williams, JAG .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (08) :1565-1579

[5] Mechanisms of electrochemical recognition of cations, anions and neutral guest species by redox-active receptor molecules [J].

Beer, PD ;

Gale, PA ;

Chen, GZ .

COORDINATION CHEMISTRY REVIEWS, 1999, 185-6 :3-36

[6] Molecular switches of fluorescence operating through metal centred redox couples [J].

Bergonzi, R ;

Fabbrizzi, L ;

Licchelli, M ;

Mangano, C .

COORDINATION CHEMISTRY REVIEWS, 1998, 170 :31-46

[7] Thermodynamic and fluorescence emission studies on chemosensors containing anthracene fluorophores.: Crystal structure of {[CuL1Cl]Cl}2•2H2O [L1 = N-(3-aminopropyl)-N′-3-(anthracen-9-ylmethyl)aminopropylethane-1,2-diamine] [J].

Bernardo, MA ;

Pina, F ;

Escuder, B ;

García-España, E ;

Godino-Salido, ML ;

Latorre, J ;

Luis, SV ;

Ramírez, JA ;

Soriano, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (06) :915-921

[8] Thermodynamic and steady-state fluorescence emission studies on metal complexes of receptors containing benzene subunits [J].

Bernardo, MA ;

Pina, F ;

Garcia-Espana, E ;

Latorre, J ;

Luis, SV ;

Llinares, JM ;

Ramirez, JA ;

Soriano, C .

INORGANIC CHEMISTRY, 1998, 37 (16) :3935-3942

[9] Interaction between silver and other heavy metal ions and the ionophore S,S-dipropyl pyridine-2,6-dicarbothioate [J].

Cattrall, RW ;

Gregorio, CG ;

Webster, RD ;

Bond, AM ;

Oldham, KB .

ANALYTICAL CHEMISTRY, 1997, 69 (16) :3353-3359

[10] FLUOROMETRIC CHEMODOSIMETRY - MERCURY(II) AND SILVER(I) INDICATION IN WATER VIA ENHANCED FLUORESCENCE SIGNALING [J].

CHAE, MY ;

CZARNIK, AW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) :9704-9705

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