A better understanding of the self-structuration of bridged silsesquioxanes

被引：160

作者：

Moreau, JJE

Pichon, BP

Man, MWC

Bied, C

Pritzkow, H

Bantignies, JL

Dieudonné, P

Sauvajol, JL

机构：

[1] Ecole Natl Super Chim Montpellier, CNRS, UMR 5076, F-34296 Montpellier 5, France

[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

[3] Univ Montpellier 2, Dynam Phases Condensees Grp, CNRS, UMR 5581, F-34095 Montpellier 5, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 02期

关键词：

hydrogen bonds; nanostructures; organic-inorganic hybrid composites; self-assembly; silsesquioxanes;

D O I：

10.1002/anie.200352485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The best solution? A highly crystalline hybrid silica has been obtained through the hydrolysis of a precursor in the solution phase. The self-organized structure of the lamellar material consists of diureido-phenylene bridging units (see picture); structural comparisons of this material and its molecular precursor show the existence of similar hydrogen-bonding interactions in both structures.

引用

页码：203 / 206

页数：4

共 25 条

[21] Solid state hydrolysis/polycondensation of alkoxysilane: Access to crystal-like silicon-based hybrid materials [J].