Length scale for the onset of Fickian diffusion in supercooled liquids

被引:162
作者
Berthier, L [1 ]
Chandler, D
Garrahan, JP
机构
[1] Univ Montpellier 2, LDV, UMR 5587, F-34095 Montpellier, France
[2] CNRS, F-34095 Montpellier, France
[3] Univ Oxford, Rudolf Peierls Ctr Theoret Phys, Oxford OX1 3NP, England
[4] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[5] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England
来源
EUROPHYSICS LETTERS | 2005年 / 69卷 / 03期
关键词
D O I
10.1209/epl/i2004-10401-5
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The interplay between self-diffusion and excitation lines in space-time was recently studied in kinetically constrained models to explain the breakdown of the Stokes-Einstein law in supercooled liquids. Here, we further examine this interplay and its manifestation in incoherent scattering functions. In particular, we establish a dynamic length scale below which Fickian diffusion breaks down, as is observed in experiments and simulations. We describe the temperature dependence of this length scale in liquids of various fragilities, and provide analytical estimates for the van Hove and self-intermediate scattering functions.
引用
收藏
页码:320 / 326
页数:7
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