Chiral polypropionate subunit by a chemoenzymatic approach

被引:7
作者
Bonini, C
Chiummiento, L
Funicello, M
Marconi, L
Righi, G
机构
[1] Univ Basilicata, Dipartimento Chim, I-85100 Potenza, Italy
[2] Univ La Sapienza, Dipartimento Chim, CNR, Ctr Studio Chim Sostanze Organ Nat, I-00185 Rome, Italy
关键词
D O I
10.1016/S0957-4166(98)00256-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Enzymatic desymmetrization of meso-4-methyl-3,5-syn-dioxolan-1,3,5,7-tetrol was found to be highly enantioselective leading to both acetylated enantiomers with high enantiomeric excess. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2559 / 2561
页数:3
相关论文
共 13 条
[1]  
[Anonymous], [No title captured]
[2]   Synthesis of the C-1-C-10 fragment of the macrolide antibiotic Nystatin A(1) from a chiral building block obtained via chemoenzymatic approach [J].
Bonini, C ;
Giugliano, A ;
Racioppi, R ;
Righi, G .
TETRAHEDRON LETTERS, 1996, 37 (14) :2487-2490
[3]   ENZYME-CATALYZED DESYMMETRIZATION OF MESO-SKIPPED POLYOLS TO USEFUL CHIRAL BUILDING-BLOCKS [J].
BONINI, C ;
RACIOPPI, R ;
VIGGIANI, L .
TETRAHEDRON-ASYMMETRY, 1993, 4 (05) :793-805
[4]   ENZYMATIC DESYMMETRIZATION OF MESO(ANTI-ANTI)-2,4-DIMETHYL-1,3,5-PENTANETRIOL [J].
CHENEVERT, R ;
COURCHESNE, G .
TETRAHEDRON-ASYMMETRY, 1995, 6 (09) :2093-2096
[5]   A convenient preparation of elements of the stereotriade [J].
Domon, L ;
Vogeleisen, F ;
Uguen, D .
TETRAHEDRON LETTERS, 1996, 37 (16) :2773-2776
[6]   An efficient synthesis of C-20-C-25 building blocks for calyculin A [J].
Hamada, Y ;
Yokokawa, F ;
Kabeya, M ;
Hatano, K ;
Kurono, Y ;
Shioiri, T .
TETRAHEDRON, 1996, 52 (24) :8297-8306
[7]   Total synthesis of (+)-conagenin [J].
Hatakeyama, S ;
Fukuyama, H ;
Mukugi, Y ;
Irie, H .
TETRAHEDRON LETTERS, 1996, 37 (23) :4047-4050
[8]  
Kim B.-M., 1991, COMPREHENSIVE ORGANI, V2, P239
[9]  
NICHOLAS A, 1891, INT MONTATSSCHR ANAT, V8, P1
[10]   BIOSYNTHESIS OF FATTY-ACID AND POLYKETIDE METABOLITES [J].
OHAGAN, D .
NATURAL PRODUCT REPORTS, 1995, 12 (01) :1-32