A convenient protocol for the α-iodination of α,β-unsaturated carbonyl compounds with I2 in an aqueous medium

被引：100

作者：

Krafft, ME ^{[1
]}

Cran, JW ^{[1
]}

机构：

[1] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

来源：

SYNLETT | 2005年 / 08期

关键词：

alpha; beta-unsaturated carbonyl compounds; alpha-iodination; aqueous medium; regioselective;

D O I：

10.1055/s-2005-868495

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of cyclic and acyclic alpha,beta-unsaturated carbonyl compounds undergo alpha-iodination exclusively, in high yields, with 12 in aqueous THF catalyzed by DMAP and quinuclidine.

引用

页码：1263 / 1266

页数：4

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