Thermal degradation studies of food melanoidins

被引:73
作者
Adams, A
Borrelli, RC
Fogliano, V
De Kimpe, N
机构
[1] Univ Ghent, Fac Biosci Engn, Dept Organ Chem, B-9000 Ghent, Belgium
[2] Univ Naples Federico II, Dept Food Sci, I-80055 Naples, Italy
关键词
Maillard reaction; food melanoidins; thermal degradation;
D O I
10.1021/jf047903m
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Food melanoidins were isolated from bread crust, coffee, and tomato sauce and their composition was investigated by thermal degradation. Among the generated volatiles, important food flavor compounds were detected: in particular furans, carbonyl compounds, 1,3-dioxolanes, pyrroles, pyrazines, pyridines, thiophenes, and phenols. The results indicated that the isolated melanoidin fractions mainly consisted of compounds formed from carbohydrates and their degradation products. Besides proteins, other food constituents were incorporated in the melanoidin structure as well, such as lipid oxidation products in tomato melanoidins and phenolic compounds in coffee melanoidins. A comparison of the thermal generation of volatiles between these food-derived melanoidins and model melanoidins prepared from a single carbonyl compound and an amino acid showed that the degradation pattern of food melanoidins is quite different from that obtained from a glucose-glycine model system.
引用
收藏
页码:4136 / 4142
页数:7
相关论文
共 28 条
[1]   Characterization of model melanoidins by the thermal degradation profile [J].
Adams, A ;
Tehrani, KA ;
Kersiene, M ;
Venskutonis, R ;
De Kimpe, N .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2003, 51 (15) :4338-4343
[2]  
Belitz H.D., 2004, FOOD CHEM, V3rd, DOI 10.1007/978-3-540-69934-7
[3]   Characterization of coloured compounds obtained by enzymatic extraction of bakery products [J].
Borrelli, RC ;
Mennella, C ;
Barba, F ;
Russo, M ;
Russo, GL ;
Krome, K ;
Erbersdobler, HF ;
Faist, V ;
Fogliano, V .
FOOD AND CHEMICAL TOXICOLOGY, 2003, 41 (10) :1367-1374
[4]   Chemical characterization and antioxidant properties of coffee melanoidins [J].
Borrelli, RC ;
Visconti, A ;
Mennella, C ;
Anese, M ;
Fogliano, V .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2002, 50 (22) :6527-6533
[5]   Intact carbohydrate structures as part of the melanoidin skeleton [J].
Cämmerer, B ;
Jalyschko, W ;
Kroh, LW .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2002, 50 (07) :2083-2087
[6]   INVESTIGATION OF THE INFLUENCE OF REACTION CONDITIONS ON THE ELEMENTARY COMPOSITION OF MELANOIDINS [J].
CAMMERER, B ;
KROH, LW .
FOOD CHEMISTRY, 1995, 53 (01) :55-59
[7]   THE CONSTITUENTS OF TOMATO FRUIT - THE INFLUENCE OF ENVIRONMENT, NUTRITION, AND GENOTYPE [J].
DAVIES, JN ;
HOBSON, GE .
CRC CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION, 1981, 15 (03) :205-280
[8]   Formation of coloured Maillard reaction products in a gluten-glucose model system [J].
Fogliano, V ;
Monti, SM ;
Musella, T ;
Randazzo, G ;
Ritieni, A .
FOOD CHEMISTRY, 1999, 66 (03) :293-299
[9]   Effect of peeling and heating on carotenoid content and antioxidant activity of tomato and tomato-virgin olive oil systems [J].
Graziani, G ;
Pernice, R ;
Lanzuise, S ;
Vitaglione, P ;
Anese, M ;
Fogliano, V .
EUROPEAN FOOD RESEARCH AND TECHNOLOGY, 2003, 216 (02) :116-121
[10]   OCCURRENCE OF PHENOLS IN COFFEE MELANOIDINS [J].
HEINRICH, L ;
BALTES, W .
ZEITSCHRIFT FUR LEBENSMITTEL-UNTERSUCHUNG UND-FORSCHUNG, 1987, 185 (05) :366-370