Cubic-C3N4 nanoparticles synthesized in CNx/TiNx multilayer films

被引:25
作者
Wang, TS [1 ]
Yu, DL
Tian, YJ
Xiao, FR
He, JL
Li, DC
Wang, WK
Li, L
机构
[1] Yanshan Univ, Coll Mat Sci, Qinhuangdao 066004, Peoples R China
[2] Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
关键词
D O I
10.1016/S0009-2614(00)01251-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cubic-C3N4 nanoparticles were synthesized in CNx/TiNx multilayer films by a nitrogen ion beam sputtering in situ titanium and graphite targets alternatively. The C-N bonding states within the CNx layers, the morphologies and structure of compounds in the films have been investigated by X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM) and X-ray diffraction (XRD), respectively. Two types of bonding states, N-sp(2)C and N-sp(3)C, exist predominantly in the CNx layer, and crystalline particles with sizes of 10-60 nm were observed in the CNx layer of the films. Their diffraction data can be assigned to the cubic-C3N4 structure. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:7 / 11
页数:5
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