Fluorous phase soluble palladium nanoparticles as recoverable catalysts for Suzuki cross-coupling and Heck reactions

被引：127

作者：

Moreno-Mañas, M ^{[1
]}

Pleixats, R ^{[1
]}

Villarroya, S ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 22期

关键词：

D O I：

10.1021/om010442z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,5-Bis(4,4'-bis(perfluorooctyl)phenyl)-1,4-pentadien-3-one stabilizes palladium(0) nanoparticles (transmission electron microscopy) formed in the reduction of palladium dichloride with methanol. These palladium colloids are soluble in-perfluorinated solvents, and they are efficient recoverable catalysts for Suzuki cross-couplings and Heck reactions under fluorous biphasic conditions.

引用

页码：4524 / 4528

页数：5

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