Surface confined pseudorotaxanes with electrochemically controllable complexation properties

被引：43

作者：

Bryce, MR

Cooke, G ^{[1
]}

Duclairoir, FMA

John, P

Perepichka, DF

Polwart, N

Rotello, VM

Stoddart, JF

Tseng, HR

机构：

[1] Heriot Watt Univ, Ctr Biomimet Design & Synth, Dept Chem, Sch Engn & Phys Sci, Edinburgh EH14 4AS, Midlothian, Scotland

[2] Univ Massachusetts, Dept Chem, Amherst, MA 01002 USA

[3] Univ Calif Los Angeles, Calif Nanosyst Inst, Los Angeles, CA 90095 USA

[4] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2003年 / 13卷 / 09期

关键词：

D O I：

10.1039/b306274k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A stable tetrathiafulvalene (TTF) functionalized self-assembled monolayer has been fabricated from compound 3. The electrochemical adjustment of the guest properties of the TTF moiety of this unit has facilitated the development of surfaces in which the 3(0) state forms a pseudorotaxane with the electron deficient macrocyclic host cyclobis(paraquat-p-phenylene) 1, and the electrochemically generated dicationic state 3(2+) forms a pseudorotaxane with the electron rich macrocyclic host 1,5-dinaphtho[38]crown-10 2.

引用

页码：2111 / 2117

页数：7

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