Black phosphorus and its composite for lithium rechargeable batteries

被引:646
作者
Park, Cheol-Min [1 ]
Sohn, Hun-Joon [1 ]
机构
[1] Seoul Natl Univ, Sch Mat Sci & Engn, Res Ctr Energy Convers & Storage, Seoul 151742, South Korea
关键词
D O I
10.1002/adma.200602592
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The transformation of amorphous red phosphorus into orthorhomhic black phosphorus is demonstrated by a simple method. ne method uses a high-energy mechanical milling technique at ambient temperature and pressure. Modification with carbon produces a composite that shows enhanced electrochemical discharge/charge behavior when used as an anode material for lithium-ion rechargeable batteries.
引用
收藏
页码:2465 / +
页数:5
相关论文
共 33 条
[21]   The crystal structure of γ-P4, a low temperature modification of white phosphorus [J].
Okudera, H ;
Dinnebier, RE ;
Simon, A .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2005, 220 (2-3) :259-264
[22]   Phosphorus nanorods -: Two allotropic modifications of a long-known element [J].
Pfitzner, A ;
Bräu, MF ;
Zweck, J ;
Brunklaus, G ;
Eckert, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (32) :4228-4231
[23]   Phosphorus remains exciting! [J].
Pfitzner, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (05) :699-700
[24]   Nano-sized transition-metaloxides as negative-electrode materials for lithium-ion batteries [J].
Poizot, P ;
Laruelle, S ;
Grugeon, S ;
Dupont, L ;
Tarascon, JM .
NATURE, 2000, 407 (6803) :496-499
[25]   Fibrous red phosphorus [J].
Ruck, M ;
Hoppe, D ;
Wahl, B ;
Simon, P ;
Wang, YK ;
Seifert, G .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (46) :7616-7619
[26]  
SHIROTANI I, 1982, MOL CRYST LIQ CRYST, V86, P1943
[27]   Study of Li(3-x)M(x)N (M:Co,Ni or Cu) system for use as anode material in lithium rechargeable cells [J].
Shodai, T ;
Okada, S ;
Tobishima, S ;
Yamaki, J .
SOLID STATE IONICS, 1996, 86-8 :785-789
[28]   A reversible solid-state crystalline transformation in a metal phosphide induced by redox chemistry [J].
Souza, DCS ;
Pralong, V ;
Jacobson, AJ ;
Nazar, LF .
SCIENCE, 2002, 296 (5575) :2012-2015
[29]   Mechanical alloying and milling [J].
Suryanarayana, C .
PROGRESS IN MATERIALS SCIENCE, 2001, 46 (1-2) :1-184
[30]  
W. Hoenle and, 1981, Z KRISTALLOGR, V155, P307