Preparation of Ag2Se and Ag2Se1-Tex nanowires by electrodeposition from DMSO baths

被引:47
作者
Chen, RZ [1 ]
Xu, DS [1 ]
Guo, GL [1 ]
Gui, LL [1 ]
机构
[1] Peking Univ, Coll Chem & Mol Engn, Inst Chem Phys, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China
关键词
selenide; nanowire; electrodeposition; magnetoresistance; silver selenide-tellurie; DMSO;
D O I
10.1016/S1388-2481(03)00133-4
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We have developed a novel electrochemical route to fabricate highly ordered stoichiometric Ag2Se nanowire arrays by electrodeposition from non-aqueous dimethyl sulfoxide (DMSO) solutions. Cyclic voltammetry technique was used to study this cathodic deposition process. X-ray energy dispersion analysis shows that stoichiometric; Ag2Se nanowires can be obtained in a wide range of deposition condition. X-ray diffraction and electron diffraction patterns demonstrate that the as-deposited nanowires are [002] oriented orthorhombic beta-Ag2Se. Furthermore, ternary Ag2Se1-xTex nanowires have been electrodeposited in mixed SeCl4-TeCl4 DMSO solutions. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:579 / 583
页数:5
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