Utilization of Natural Sunlight and Air in the Aerobic Oxidation of Benzyl Halides

被引:213
作者
Su, Yijin [1 ]
Zhang, Liangren [1 ]
Jiao, Ning [1 ,2 ]
机构
[1] Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomitnet Drugs, Beijing 100191, Peoples R China
[2] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
基金
美国国家科学基金会;
关键词
VISIBLE-LIGHT PHOTOCATALYSIS; PHOTOREDOX CATALYSIS; MOLECULAR-OXYGEN; PYRIDINIUM SALTS; FINE CHEMICALS; DIOXYGEN; ALKYNES; EFFICIENT; RADICALS; ALCOHOLS;
D O I
10.1021/ol2002013
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel, efficient oxidation of alpha-aryl halogen derivatives to the corresponding alpha-aryl carbonyl compounds at room temperature has been disclosed. Natural sunlight and air are successfully utilized in this approach through the combination of photocatalysis and organocatalysis. A plausible mechanism was proposed on the basis of the mechanistic studies.
引用
收藏
页码:2168 / 2171
页数:4
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