High mobility of ceria films on zirconia at moderate temperatures

被引:23
作者
Costa-Nunes, O [1 ]
Gorte, RJ [1 ]
Vohs, JM [1 ]
机构
[1] Univ Penn, Dept Chem & Biomol Engn, Philadelphia, PA 19104 USA
关键词
D O I
10.1039/b416670a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thin ceria films supported on yttria-stabilized zirconia are shown to be highly mobile at relatively moderate temperatures and their morphology depends on the gas environment to which they have been exposed.
引用
收藏
页码:1520 / 1522
页数:3
相关论文
共 16 条
[1]   Advanced anodes for high-temperature fuel cells [J].
Atkinson, A ;
Barnett, S ;
Gorte, RJ ;
Irvine, JTS ;
Mcevoy, AJ ;
Mogensen, M ;
Singhal, SC ;
Vohs, J .
NATURE MATERIALS, 2004, 3 (01) :17-27
[2]   Recent advances in materials for fuel cells [J].
Brandon, NP ;
Skinner, S ;
Steele, BCH .
ANNUAL REVIEW OF MATERIALS RESEARCH, 2003, 33 :183-213
[3]   Structure of oxide overlayer studied by energy dispersive X-ray diffraction [J].
Dmowski, W ;
Egami, T ;
Gorte, R ;
Vohs, J .
PHYSICA B, 1996, 221 (1-4) :420-425
[4]   Energy-dispersive surface X-ray scattering study of thin ceria overlayer on zirconia: Structural evolution with temperature [J].
Dmowski, W ;
Mamontov, E ;
Egami, T ;
Putna, S ;
Gorte, R .
PHYSICA B, 1998, 248 :95-100
[5]   Reaction of NO on CeO2 and Rh/CeO2 thin films supported on α-Al2O3(0001) and YSZ(100) [J].
Ferrizz, RM ;
Egami, T ;
Wong, GS ;
Vohs, JM .
SURFACE SCIENCE, 2001, 476 (1-2) :9-21
[6]   Novel SOFC anodes for the direct electrochemical oxidation of hydrocarbons [J].
Gorte, RJ ;
Vohs, JM .
JOURNAL OF CATALYSIS, 2003, 216 (1-2) :477-486
[7]   Use of CeO2-based oxides in the three-way catalysis [J].
Kaspar, J ;
Fornasiero, P ;
Graziani, M .
CATALYSIS TODAY, 1999, 50 (02) :285-298
[8]   Structural characterization of the CeO2/YSZ(111) catalytic system synthesized using simulated amorphization and recrystallization [J].
Maicaneanu, SA ;
Sayle, DC ;
Watson, GW .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (50) :12481-12489
[9]  
Mogensen M, 2002, CATALY SCI, V2, P453, DOI 10.1142/9781860949654_0015
[10]   Direct oxidation of hydrocarbons in a solid-oxide fuel cell [J].
Park, SD ;
Vohs, JM ;
Gorte, RJ .
NATURE, 2000, 404 (6775) :265-267