Catalytic and enantioselective allylic C-H activation with donor-acceptor-substituted carbenoids

被引：63

作者：

Davies, HML ^{[1
]}

Nikolai, J ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2005年 / 3卷 / 23期

关键词：

D O I：

10.1039/b509425a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this perspective we give an overview of enantioselective C-H activation at allylic sites by means of rhodium(II)-stabilized donor-acceptor-substituted carbenoids. This methodology has been proven to be both an equivalent to established asymmetric reaction sequences and a new synthetic approach with no established counterpart in organic synthesis.

引用

页码：4176 / 4187

页数：12

共 71 条

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