Catalytic and enantioselective allylic C-H activation with donor-acceptor-substituted carbenoids

被引:63
作者
Davies, HML [1 ]
Nikolai, J [1 ]
机构
[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
关键词
D O I
10.1039/b509425a
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In this perspective we give an overview of enantioselective C-H activation at allylic sites by means of rhodium(II)-stabilized donor-acceptor-substituted carbenoids. This methodology has been proven to be both an equivalent to established asymmetric reaction sequences and a new synthetic approach with no established counterpart in organic synthesis.
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页码:4176 / 4187
页数:12
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