Catalytic and enantioselective allylic C-H activation with donor-acceptor-substituted carbenoids

被引：63

作者：

Davies, HML ^{[1
]}

Nikolai, J ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2005年 / 3卷 / 23期

关键词：

D O I：

10.1039/b509425a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this perspective we give an overview of enantioselective C-H activation at allylic sites by means of rhodium(II)-stabilized donor-acceptor-substituted carbenoids. This methodology has been proven to be both an equivalent to established asymmetric reaction sequences and a new synthetic approach with no established counterpart in organic synthesis.

引用

页码：4176 / 4187

页数：12

共 71 条

[41] DAVIES HML, 2005, ANGEW CHEM, V117, P1761
[42] Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds
Desai, LV
Hull, KL
Sanford, MS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (31) : 9542 - 9543
[43] Doyle M. P., 1998, Modern Catalytic Methods for Organic Synthesis with Diazo Compounds: From Cyclopropanes to Ylides
[44] Dyker G, 1999, ANGEW CHEM INT EDIT, V38, P1699, DOI 10.1002/(SICI)1521-3773(19990614)38:12<1698::AID-ANIE1698>3.0.CO
[45] 2-6
[46] Eames J, 2000, ANGEW CHEM INT EDIT, V39, P885, DOI 10.1002/(SICI)1521-3773(20000303)39:5<885::AID-ANIE885>3.0.CO
[47] 2-2
[48] Harrowven D. C., 2005, ANGEW CHEM, V117, P1247
[49] Total synthesis of (-)-colombiasin A and (-)-elisapterosin B
Harrowven, DC
Pascoe, DD
Demurtas, D
Bourne, HO
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (08) : 1221 - 1222
[50] Total synthesis of elisabethin A: Intramolecular Diels-Alder reaction under biomimetic conditions
Heckrodt, TJ
Mulzer, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (16) : 4680 - 4681

← 1 2 3 4 5 6 7 8 →